From memory I think it has a 6.3 or 6.5mm spear, I personally wouldn't go above 2 x 14mm bands which would also be beneficial as 14mm bands are noticeably easier to pull back than the stock 18mm band, I have an Omer cayman and I think the excaliber also has 18mm bands as standard. Were are you fishing and what do you expect to spear?
I agree with Pinniped72's post above. Presumably your spear had 2 notches to accept a second wishbone? 2x14mm seems like a pretty cool configuration - but unusual (outside of Hawaii). Probably works best using all bulk rubber though (can you buy screw-in 14mm rubbers?). We estimated that 2x14mm would be about the same or slightly more powerful than 1x20mm (but see my comments on bulk rubber diameters below*).
Re. using a supplemental 14mm band with your existing 18mm band, I reckon that would probably work but might over-power your spear if it is particularly slim (what diameter is it?). My Omers have 6.3mm spears, my RA had 6.6mm but RA offers at least 2 sizes bigger than that and RA fit larger diameter spears on their 2x16mm Tuna model - 7.2mm perhaps? - to deal with the extra power).
Another option occurred to me: remove your screw-in bands and replace them with a single 3/4" bulk rubber loop. *Bulk rubber sizes aren't precise but they typically offer 3/4" rubber which is variously referred to as 19/20mm (or possibly 18mm). This is what I have done on my Omer XXV75. The advantages of this are:
(1) There is a greater length off rubber is in play because it is goes right to & through the muzzle hole up front (RA reckon their closed muzzles use about 10cm more rubber than an equivalent screw in band set-up!
(2) The American bulk rubber used on most railguns is generally more powerful (and harder to load, especially when new) at least partly because the walls are significantly thicker than typical screw-in bands, and the hole in the middle is consequently smaller.
(3) Bulk rubber is significantly cheaper. Shop around. spearitco.com in the USA sell on their own website, ebay and I think I saw them on Amazon recently. I bought rubber from them & it was very fresh (I keep my spare rubbers, sealed in a plastic bag in the deep freeze to keep them fresh). I think European brands (e.g. Omer, Dessault) now offer "circular" bands - I can't comment on their power/price.
(4) I was also able to remove the metal muzzle wishbone & screw-in fittings from my XXV (this is something peculiar to certain Omer models). Which (along with the lighter Dyneema wishbone) help offset any weight increase from the extra rubber [ref. to #1 & #2 above].
This seemed like a simple, cheap, effective alternative to me but you'll need to figure out what you will use for a wishbone (I used Dyneema which requires the wishbone notches on the spear to be grooved & smoothed - easy for me as I had an RA spear to use as my guide).
Looks like somebody already did something similar here with a carbon excalibur:
https://forums.deeperblue.com/threads/good-tune-for-omer-excalibur-carbonium-120.71294/