In the lab we used to use tanks of pure gases such a nitrogen, argon, helium, CO2, etc. for various purposes, and in the safety newsletters reports would appear from time to time of someone getting into trouble when there was release into a room that displaced the oxygen, or when they got a shot of pure gas that displaced the air in their lungs. It's insidious for 2 reasons- there's no scent to most of these gases, and since you can't detect O2 levels in your lungs, nothing seems to be wrong, because the CO2 is clearing normally from your lungs.
If someone does black out from breathing a pure gas without oxygen, you shouldn't just blow on their faces or slap 'em to get 'em breathing again. It's a big job to get the gas out of the lungs and some fresh O2 in there, so you should start artificial respiration as soon as you can.
Concerning CO2 gas, many of my colleagues would use it to kill small animals- fish, mice, young rabbits, etc., for experiments. I personally favour the cervical dislocation method since it is instant, and I think death by gassing is actually a bit cruel, but some folks didn't have the stomach for CD, so they'd put 'em in a container and feed in pure CO2. The beasts always died within less than 2 minutes. Note that it takes much longer for CO2 to kill a large animal, and this should never be used for animals larger than about 2 kg IMO.
People might find this article interesting:
http://www.csb.gov/assets/document/SB-Nitrogen-6-11-03.pdf