One thing I don't get. Experienced free divers talk about being in the danger zone. Surely a zone has limits.
Yes, of course, you are right, there is a safe and a danger zone. And they have their limits too.
The only problem is that they are never the same and changing all the time with countless of factors and change from one dive to another, and that you never know in advance where the limit is. If you have a buddy or are very lucky, you perhaps learn where the limit was after crossing it, but if there is nobody to help you, there is relatively small chance you survive it.
As Simo wrote, there are many dead freedivers, some of them belonging to the very top elite, who were experienced and believed they knew well their limits, and took the risk to dive alone. Now they rest in peace as a memento for us others.
So having a buddy is the best way to reduce the risk, but then again simply having a buddy who has no experience with freediving safety or who does not watch you closely, is not of a big help. His role may be then reduced on calling the coast guard to recover your body.
I know that those who did some serious freediving training and/or participated on competitions, and know how easy it is to black out without seing it coming, they are much more hesitating to dive alone.
Still, there are and there always will be people freediving alone. This topic was frequently discussed here on DB, and you will find plenty of threads advising how to limit the risks. The best one is and always will be a knowledgeable buddy, but you can avoid different mistakes, or learn habits that may save your life. Also the
Freediving Recovety Vest may help protecting your life (although it is not a buddy replacement!). Avoding hyperventilation, using a float, hydrating well, learning to release the belt buckle keeping it in hand on the ascent, and many other advices were discussed in other threads that you will find in the archive. So if you decide diving alone, leep on mind that you will not avoid the serious risk, but that there are ways to prevent unnecessarily increasing it.